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Modification of NanoCrystalline Cellulose (NCC) by Hyperbranched Polymer
Objectives: The surface modification of NanoCrystalline Cellulose (NCC) recently has been paid attention due to the increasing opportunities in the application. The objective of this paper is to modify the surface of NCC by the HyperBranched Polymer (HBP) with hydroxyl terminal groups ends. Methods/Statistical Analysis: The NCC surfaces were modified with HBP using solvent evaporation methods. First, the NCC was synthesized via ultrasound assisted acid hydrolysis process and the obtained NCC was surface coated by using HBP with different concentration through solvent evaporation technique. Finally, the obtained NCC and Modified NCC were characterized by using FTIR, XRD and TGA. Findings: Results revealed that there are significant differences of FTIR pattern analysis indicated that the NCC has been modified, however the modification NCC with HBP under various conditions did not change the X-ray patterns of NCC which indicates that the HBP only coated on the surface of NCC. Application/Improvements: This modification of NCC showed promising results which can be used for various applications.
Adsorption, Hyper-Branched Polymer (HBP), Modification, Nanocrystalline Cellulose (NCC)
- Eichhorn SJ. Cellulose nanowhiskers: promising materials for advanced applications. Soft Matter. 2011; 7:303–15. https://doi.org/10.1039/C0SM00142B
- Silvério HA, Neto WPF, Dantas NO, Pasquini D. Extraction and characterization of cellulose nanocrystals from corncob for application as a reinforcing agent in nanocomposites. Industrial Crops and Products. 2013; 44:427–36. https:// doi.org/10.1016/j.indcrop.2012.10.014
- Fan J, Li Y. Maximizing the yield of nanocrystalline cellulose from cotton pulp fiber. Carbohydrate Polymers. 2012; 88(4):1184–8. https://doi.org/10.1016/j.carbpol. 2012.01.081
- Liu Z, Xie C. Preparation and morphology of nanocrystalline cellulose from bamboo pulp. In the Proceedings of the 55th International Convention of Society of Wood Science and Technology - Beijing, China. 2012 Aug. p. 1–6.
- Brito BSL, Pereira FV, Putaux JL, Jean B. Preparation, morphology and structure of cellulose nanocrystals from bamboo fibers. Cellulose. 2012; 19(5):1527–36. https://doi. org/10.1007/s10570-012-9738-9
- Li W, Yue J, Liu S. Preparation of nanocrystalline cellulose via ultrasound and its reinforcement capability for poly (vinyl alcohol) composites. Ultrasonics Sonochemistry. 2012; 19(3):479–85. https://doi.org/10.1016/j.ultsonch. 2011.11.007 PMid:22153226
- Santosa RMD, Netoa WPF, Silvérioa HA, Martinsa DF, Dantasb NO, Pasquinia D. Cellulose nanocrystals from pineapple leaf, a new approach for the reuse of this agrowaste. Industrial Crops and Products. 2013; 50:707–14. https://doi.org/10.1016/j.indcrop.2013.08.049
- Sheltami RM, Abdullah I, Ahmad I, Dufresne A, Kargarzadeh H. Extraction of cellulose nanocrystals from mengkuang leaves ( Pandanus tectorius ). Carbohydrate Polymers. 2012; 88(2):772–9. https://doi.org/10.1016/j. carbpol.2012.01.062
- Chenampulli S, Unnikrishnan G, Sujith A, Thomas S, Francis T. Cellulose nano-particles from Pandanus: viscometric and crystallographic studies. Cellulose. 2012; 20(1):429–38. https://doi.org/10.1007/s10570-012-9831-0
- Rosaa MF, Medeirosb ES, Malmonged JA, Gregorskib KS, Woodb DF, Mattosoc LHC, Glennb G, Ortsb WJ, Imamb SH. Cellulose nanowhiskers from coconut husk fibers: Effect of preparation conditions on their thermal and morphological behavior. Carbohydrate Polymers. 2010; 81(1):83–92. https://doi.org/10.1016/j.carbpol.2010.01.059
- Haafiz MKM, Hassan A, Zakaria Z, Inuwa IM. Isolation and characterization of cellulose nanowhiskers from oil palm biomass microcrystalline cellulose. Carbohydrate Polymers . 2014; 103:119–25. https://doi.org/10.1016/j. carbpol.2013.11.055 PMid:24528708
- Tehrani AD, Basiryan A. Dendronization of cellulose nanowhisker with cationic hyperbranched dendritic polyamidoamine. Carbohydrate Polymers. 2015; 120:46– 52. https://doi.org/ 10.1016/ j.carbpol. 2014.12. 004 PMid:25662686
- Tana C, Penga J, Lina W, Xinga Y, Xua K, Wua J, Chena M. Role of surface modification and mechanical orientation on property enhancement of cellulose nanocrystals/polymer nanocomposites. European Polymer Journal. 2015; 62:186– 97. https://doi.org/10.1016/j.eurpolymj.2014.11.033
- FluidChe 2017 Available from: http://fluidsche.ump.edu.my/index.php/en/
- The Center of Excellence for Advanced Research in Fluid Flow (CARIFF) Available from: http://cariff.ump.edu.my/
- Natural resources products prospects - International Conference on Fluids and Chemical Engineering FluidsChE 2017 Malaysia, ). Indian Journal of science and technology.2017; S2(1).
- University Malaysia Pahang. Available from: www.ump.edu.my
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