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Influence of Ammonium based Compounds for Gas Hydrate Mitigation: A Short Review
Objectives: In natural gas transmission pipelines hydrate formation is major flow assurance challenge. This communuication presents as brief review focuses on the potentially applicable area of Ammonium based compounds (ACs) as gas hydrate inhibition. Methods/Statistical Analysis: For avoiding gas hydrate formation, oil and gas industry spent millions of dollar annually without any permanent solution. In most of the cases insertion of chemicals (inhibitor) established as the utmost supreme route for gas hydrate mitigation. Quantary ammonium salts had widely been applied as commercial hydrate inhibitors. Ammonium based Ionic Liquids (AILs) also recently applies as work as potential gas hydrate inhibitor for hydrate mitigation. Findings: The systematic review on ACs proves that higher concentration of ACs provides more effective thermodynamic inhibition. The alkyl chain length of ACs playsan important part, as the chain length increases it decrease their effectiveness as inhibitors. Usually, imidazolium based ILs employed as gas hydrate inhibitors contains fluorinated anions which categorized as toxic compound. ACs holds the strong tendency to act as the dual function chemical inhibitor for possible replacement of widely used imidazolium based ILs due to their cheaper source, easy synthesis along with fairly better environmentally friendly nature. Application/Improvements: This study will highlight the recent advancements achieved in the field of ACs, highlighting the vigorous prospects of ACs as potential gas hydrate inhibitors and provide the avenue to accomplish flow assurance problems caused due to gas hydrates
Ammonium based Compounds (ACs), AIL, Gas Hydrate, Inhibitors, KHI, THI.
- Koh CA, Sloan ED. Natural gas hydrates: Recent advances and challenges in energy and environmental applications. AIChE Journal. 2007; 53(7):1632–43. https://doi. org/10.1002/aic.11219
- Sum AK, Koh CA, Sloan ED. Clathrate hydrates: From laboratory science to engineering practice. Industrial and Engineering Chemistry Rsearch. 2009 Aug 19; 48(16):7457– 65. https://doi.org/10.1021/ie900679m
- Koh C, Sloan ED, Sum AK, Wu DT. Fundamentals and applications of gas hydrates. Annual Rreview of Chemical and Biomolecular Engineering. 2011 Jan; 2:237–57. https:// doi.org/10.1146/annurev-chembioeng-061010-114152 PMid:22432618
- Drive C, Carroll J. Natural gas hydrates: A guide for engineers. Industrial and Engineering Elsevier Science and Technology Books; 2009. p. 277.
- Sloan ED, Koh CA. Clathrate hydrates of natural gases. 3rd ed. 2007. p. 721. https://doi.org/10.1201/9781420008494 6. Sabil KM, Nashed O, Lal B, Ismail L, Japper-Jaafar A.
- Experimental investigation on the dissociation conditions of methane hydrate in the presence of imidazolium-based ionic liquids. Journal of Chemical Thermodynamics. 2015; 84(5):7–13. https://doi.org/10.1016/j.jct.2014.12.017
- Nasir Q, Lau KK, Lal B. Enthalpies of dissociation of pure methane and carbon dioxide gas hydrate. International Journal of Chemical, Nuclear, Metallurgical and Materials Engineering. 2014; 8(8):785–8.
- Nasir Q, Lau KK, Lal B, Sabil KM. Hydrate dissociation condition measurement of CO2‑ Rich mixed gas in the presence of methanol/ethylene glycol and mixed methanol/ ethylene glycol + electrolyte aqueous solution. Journal of Chemical and Engineering Data. 2014; 59(11):3920–6. https://doi.org/10.1021/je5008313
- Jensen L. Experimental investigation and molecular simulation of gas hydrates. Technical University of Denmark; 2010.
- Obanijesu EO, Pareek V, Tade MO. Hydrate formation and its influence on natural gas pipeline internal corrosion rate. NAFTA. 2011; 62(5–6):164–73.
- Sloan ED, Koh CA. Gas hydrates of natural gases. 3rd ed. London; New York: CRC Press LLC; 2008. p. 693.
- Erfani A, Varaminian F, Muhammadi M. Gas hydrate formation inhibition using low dosage hydrate inhibitors. 2nd National Iranian Conference on Gas Hydrate (NICGH); Iran. 2013.
- Koh CA, Westacott RE, Zhang W, Hirachand K, Creek JL, Soper AK. Mechanisms of gas hydrate formation and inhibition. Fluid Phase Equilibria. 2002 Mar; 194–197:143–51. https://doi.org/10.1016/S0378-3812(01)00660-4
- Samimi A. Preventing hydrate formation in gas transporting pipe lines with synthetic inhibitors. International Journal of science and investigations. 2012; 1(9):48–50.
- Kelland MA. History of the development of low dosage hydrate inhibitors. Energy and Fuels. 2006; 20(3):825–47. https://doi.org/10.1021/ef050427x
- Sloan D, Koh C, Sum A. Natural gas hydrates in flow assurance. Atlantis: Gulf Professional Publishing; 2010. p . 213.
- Farzaneh-gord M, Izadi S, Pishbin SI, Sheikhani H. Thermodynamic analysis of medium pressure reciprocating natural gas expansion engines. Polish Journal of Chemical Technology. 2015; 17(2):119–25. https://doi.org/10.1515/ pjct-2015-0039
- Zanota ML, Dicharry C, Graciaa A. Hydrate plug prevention by quaternary ammonium salts. Energy and Fuels. 2005; 19(11):584–90. https://doi.org/10.1021/ef040064l
- Khan MS, Seng C, Kurnia KA, Cornelius B, Lal B. Application of COSMO-RS in investigating ionic liquid as thermodynamic hydrate inhibitor for methane hydrate. Procedia Engineering. 2016; 148(2016):862–9. https://doi.org/10.1016/j.proeng.2016.06.452
- Bavoh CB, Lal B, Nashed O, Khan MS, Lau KK, Bustam MA. COSMO-RS: An ionic liquid prescreening tool for gas hydrate mitigation. Chinese Journal of Chemical Engineering. Elsevier B.V. 2016 Nov; 24(11):1619–24.
- Tariq M, Rooney D, Othman E, Aparicio S, Atilhan M, Khraisheh M. Gas hydrate inhibition: a review of the role of ionic liquids. Industrial and Engineering Chemistry Research. 2014 Nov 19; 53(46):17855–68. https://doi.org/10.1021/ie503559k
- Partoon B, Wong NMS, Sabil KM, Nasrifar K, Ahmad MR. A study on thermodynamics effect of [EMIM]-Cl and [OH-C2MIM ]-Cl on methane hydrate equilibrium line. Fluid Phase Equilibria. Elsevier B.V. 2013; 337:26–31.
- Stojanovic A, Morgenbesser C, Kogelnig D, Krachler R, Keppler BK. Quaternary ammonium and phosphonium ionic liquids in chemical and environmental engineering. In: Kokorin PA, editor. Ionic Liquids: Theory, Properties, New Approaches. 1st ed. Croatia: InTech; 2011. p. 657–80. https://doi.org/10.5772/14340
- Kelland MA. Production chemicals for the oil and gas industry. 2nd ed. CRC Press Taylor and Francis; 2014. p. 432. https://doi.org/10.1201/b16648
- Jiang Y, Geng T, Li Q. Synthesis of quaternary ammonium salts with novel counterions. Journal of Surfactants and Detergents. 2012; 15(1):67–71. https://doi.org/10.1007/ s11743-011-1289-9
- Mady MF, Kelland MA. Fluorinated quaternary ammonium bromides: Studies on their tetrahydrofuran hydrate crystal growth inhibition and as synergists with polyvinylcaprolactam kinetic gas hydrate inhibitor. Energy and Fuels. 2013; 27(9):5175−81. https://doi.org/10.1021/ef401292m
- Mohamed NA. Avoiding gas hydrate problems in qatar oil and gas industry: environmentally friendly solvents for gas hydrate inhibition. Qatar University; 2014.
- Chua PC, Kelland M A. Tetra(iso-hexyl)ammonium bromidethe most powerful quaternary ammonium-based tetrahydrofuran crystal growth inhibitor and synergist with polyvinylcaprolactam kinetic gas hydrate inhibitor. Energy and Fuels. 2012 Feb 16; 26(2):1160–8. https://doi.org/10.1021/ef201849t
- Magnusson CD, Kelland MA. Study on the synergistic properties of quaternary phosphonium bromide salts with N‑ vinylcaprolactam based kinetic hydrate inhibitor polymers. Energy and Fuels. 2014; 28:6803–10. https://doi.org/10.1021/ef501545p
- Nagano Y, Mizuno H, Sakiyama M, Fujiwara T, Kondo Y. Hydration enthalpy of tetra-n-butylammonium ion. The Journal of Physical Chemistry. 1991 Mar 1; 95(6):2536–40. https://doi.org/10.1021/j100159a079
- Zheng Z. Molecular dynamics simulations on the inhibition of methane hydrates. Iowa State University; 2010.
- Sefidroodi H, Chua PC, Kelland MA. THF hydrate crystal growth inhibition with small anionic organic compounds and their synergistic properties with the kinetic hydrate inhibitor poly(N-vinylcaprolactam). Chemical Engineering Science. 2011 May; 66(10):2050–6. https://doi.org/10.1016/j.ces.2011.01.014
- Li X-S, Liu Y-JJ, Zeng Z-YY, Chen Z-YY, Li G, Wu H-JJ. Equilibrium hydrate formation conditions for the mixtures of methane + ionic liquids + water. Journal of Chemical and Engineering Data. 2011 Jan 13; 56(1):119–23. https://doi.org/10.1021/je100987q
- Keshavarz L, Javanmardi J, Eslamimanesh A, Mohammadi AH. Experimental measurement and thermodynamic modeling of methane hydrate dissociation conditions in the presence of aqueous solution of ionic liquid. Fluid Phase Equilibria. Elsevier B.V. 2013 Sep; 354(2):312–8.
- Tariq M, Connor E, Thompson J, Khraisheh M, Atilhan M, Rooney D. Doubly dual nature of ammonium-based ionic liquids for methane hydrates probed by rocking-rig assembly. RSC Advances. 2016; 6(28):23827–36. https:// doi.org/10.1039/C6RA00170J
- Khan MS, Lal B, Partoon B, Kok L, Azmi B. Experimental evaluation of a novel thermodynamic inhibitor for CH4 and CO2 hydrates. Procedia Engineering. 2016; 148(2016):932– 40. https://doi.org/10.1016/j.proeng.2016.06.433
- Atilhan M, Aparicio S, Benyahia F, Deniz E. Natural gas hydrates. In: Al-Megren H, editor. Advances in Natural Gas Technology. Croatia: InTech; 2012. p. 194–212. https://doi.org/10.5772/38301
- Storr MT, Taylor PC, Monfort JP, Rodger PM. Kinetic inhibitor of hydrate crystallization. Journal of the American Chemical Society. 2004; 126(5):1569–76. https://doi.org/10.1021/ja035243g PMid:14759217
- Suresh A, Choi HL, Kannan N, Rajagopal K. Biochemical methane potentials and organic matter degradation of swine slurry under mesophilic anaerobic digestion. Indian Journal of Science and Technology. 2016; 9(6):1–6. https:// doi.org/10.17485/ijst/2016/v9i6/77183
- Kim OK, An KB, Kim JH, Kang SW, Baek HH. Instantaneous temperature measuring system design of skin tissue in medical CO2 laser device with power and pulse time variation. Indian Journal of Science and Technology. 2015 Oct; 8(26):1–5. https://doi.org/10.17485/ijst/2015/v8iS5/61442 https://doi.org/10.17485/ijst/2015/v8i26/81202
- Masohan A, Ahmed M, Nirmal SK, Kumar A, Garg MO. A simple pH-based method for estimation of CO2 absorbed in alkanolamines. Indian Journal of Science and Technology. 2009; 2(4):59–64.
- Goswami P, Barua AG. Absorption of 9.6 μm CO2 laser beam by nitrous oxide. Indian Journal of Science and Technology. 2012; 5(8):3174–6.
- Rezvani H, Shahtahmassebi N, Roknabadi MR, Arabshahi H. The effect of deposition parameters on the sensing behaviors of the SnO2: Cu nano-structure thin films including CO2-gas sensor solution preparation. Indian Journal of Science and Technology. 2010 Jun; 3(6):627–9.
- Earle MJ, Seddon KR. Ionic liquids. Green solvents for the future. Pure and Applied Chemistry. 2000; 72(7):1391–8. https://doi.org/10.1351/pac200072071391
- Kogelnig D, Stojanovic A, Galanski M, Groessl M, Jirsa F, Krachler R, et al. Greener synthesis of new ammonium ionic liquids and their potential as extracting agents. Tetrahedron Letters. 2008; 49:2782–5. https://doi.org/10.1016/j.tetlet.2008.02.138
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