Oxidation of Cinnnamic Acid by Bipyridinium Chlorochromate – Rate Determination at Various Temperatures

Padma Priya   and Subramanium

doi:10.17485/ijst/2015/v8i32/87697

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Oxidation of Cinnnamic Acid by Bipyridinium Chlorochromate – Rate Determination at Various Temperatures

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Indian Journal of Science and Technology

DOI: 10.17485/ijst/2015/v8i32/87697

Year: 2015, Volume: 8, Issue: 32, Pages: 1-6

Original Article

Oxidation of Cinnnamic Acid by Bipyridinium Chlorochromate – Rate Determination at Various Temperatures

Padma Priya^1* and Subramanium²

¹ Bharath University, Selaiyur, Chennai – 600073, Tamil Nadu, India; [email protected]
²D. G. Vaishnav College, Arumbakkam, Chennai – 600106, Tamil Nadu, India

This work is licensed under a Creative Commons Attribution 4.0 International License.

Abstract

The kinetics of oxidation of cinnamic acid by BPCC in aqueous acetic acid (50%-50% v/v) in the presence of sulphuric acid has been studied. In order to arrive at a correlation between the synthetic efficacy and structure of reagent, the kinetics of oxidation of cinnamic acid with BPCC has been carried out in aqueous acetic acid. The reaction exhibit first order dependence on both the oxidant and substrate concentrations. In this part we have studied oxidation of cinnnamic acid by bipyridiniumchlorochromate and determined rate of the reaction at various temperature.
Keywords: Bipyridiniumchlorochromate, Cinnamic Acid, Correlation, First Order