Corrosion Inhibition of Mild Steel by Newly Synthesized 1-[(4-nitrophenyl)methyl]-4-(pyridin-2- yl)piperazine in HCl Acid Medium

S Anbalagan; M Ravishankar; S Sivakumar; M Sivakumar; E Krishnan

doi:10.17485/IJST/v16i45.2276

Article

Corrosion Inhibition of Mild Steel by Newly Synthesized 1-[(4-nitrophenyl)methyl]-4-(pyridin-2- yl)piperazine in HCl Acid Medium

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Indian Journal of Science and Technology

DOI: 10.17485/IJST/v16i45.2276

Year: 2023, Volume: 16, Issue: 45, Pages: 4211-4224

Original Article

Corrosion Inhibition of Mild Steel by Newly Synthesized 1-[(4-nitrophenyl)methyl]-4-(pyridin-2- yl)piperazine in HCl Acid Medium

S Anbalagan^1,2, M Ravishankar^1*, S Sivakumar³, M Sivakumar³, E Krishnan⁴

¹Department of Chemistry, Rajah Serfoji Government College, Affiliated to Bharathidhasan University, Thanjavur, 613005, Tamil Nadu, India
²Department of Chemistry, Laxminarayana College of Arts & Science (women), Dharmapuri, Tamil Nadu, India
³Department of Chemistry, E. R. K Arts and Science College, Dharmapuri, Tamil Nadu, India
⁴Department of Chemistry, P.S.A Arts and Science College, Dharmapuri, Tamil Nadu, India

*Corresponding Author
Email: [email protected]

Received Date:07 September 2023, Accepted Date:08 October 2023, Published Date:06 December 2023

This work is licensed under a Creative Commons Attribution 4.0 International License.

Abstract

Objectives: To use the newly synthesized efficient organic corrosion inhibitor 1-[(4-nitrophenyl)methyl]-4-(pyridin-2-yl)piperazine (NMPP) to carry out on mild steel corrosion inhibition study. Methods: The 1-[(4-nitrophenyl)methyl]-4-(pyridin-2-yl)piperazine (NMPP) organic inhibitor was synthesized by condensation polymerization. The organic inhibitor NMPP, was chara cterized by Fourier transform infrared (FTIR), and high resolution scanning electron microscope (HR-SEM). The inhibition action of the polymer composite was investigated by conventional weight loss method, and electrochemical impedance spectroscopy (EIS). Findings: The maximum corrosion inhibition efficiency of 88.34 % was obtained at concentration level of 6 % at 303K. The results revealed NMPP as a mixed type corrosion inhibitor, the thermodynamic and kinetic parameters also revealed adsorption of catalyst on to mild surface as exothermic and the adsorption was confirmed by conventional weight loss method. Novelty: FT-IR analysis reveals that predominant peaks are the interaction between inhibitor and mild steel surfaces. The morphology of mild steel coupons was investigated by HR-SEM. The HR-SEM results showed novel inhibitor to have inhibited corrosion on mild steel in 1 M HCL on CO2 environment.

Keywords: Novel inhibitor, Mild steel, HRSEM, NMPP and Corrosion Inhibition

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Copyright

© 2023 Anbalagan et al. This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited. Published By Indian Society for Education and Environment (iSee)