Indian Journal of Science and Technology
Year: 2022, Volume: 15, Issue: 30, Pages: 1473-1483
P Gershom Jebaraj1*, V Sivashankar2
1Research Scholar, Reg.No. 18231282131041, Department of Physics, St. Xavier’s College (Autonomous), Palayamkottai, Affiliated to Manonmaniam Sundaranar University, Tirunelveli, India
2Assistant Professor, Department of Physics, St.Xavier’s College (Autonomous), Palayamkottai, Affiliated to Manonmaniam Sundaranar University, Tirunelveli, India
Email: [email protected]
Received Date:01 April 2022, Accepted Date:25 May 2022, Published Date:06 August 2022
Objectives: To grow crystal of inorganic material Rubidium sulfate by doping with an organic material L-leucine. Methods: Crystal has been grown by solution method. Crystallographic studies were done. Mechanical studies were carried out to find the mechanical strength and other parameters. Dielectric studies of L-leucine doped rubidium sulfate crystals were carried out to evaluate dielectric constant, dielectric loss and activation energy. UV-visible- NIR spectral studies were done in the wavelength range 200-1100 nm. Second order Non Linear Optical (NLO) studies of the grown crystal of LLRS were carried out by Kurtz-Perry technique. Findings: The grown LLRS crystal is observed to be crystallizing in orthorhombic structure by single crystal XRD studies. The optical band gap of LLRS crystal was found to be slightly more than that of undoped rubidium sulphate crystal. The SHG efficiency of LLRS crystal is observed to be 0.61 times that of the reference KDP sample. Dielectric parameters are found to decrease with increase in frequency. Dielectric constant and dielectric loss factor increase when the temperature of the samples increases. AC conductivity increases with increase of temperature. Activation energy is increasing when the frequency increases. The band gap value is found to be 4.43 eV for undoped rubidium sulfate crystal. For L-leucine doped rubidium sulfate (LLRS) crystal, the optical band gap is 4.48 eV. From the Microhardness teat, it is observed that the hardness increases with increase of the applied load for both the samples and this is due to reverse indentation size effect. Novelty: In this study, as a novel work, a very first attempt has been made to combine an organic material L-leucine with an inorganic crystal viz. rubidium sulfate to alter its physical and chemical properties.
Keywords: Inorganic Single Crystal; Crystal Structure; Mechanical Properties; Dielectric properties; Optical Properties; Spectral Properties
© 2022 Jebaraj & Sivashankar. This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.
Published By Indian Society for Education and Environment (iSee)
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