• P-ISSN 0974-6846 E-ISSN 0974-5645

Indian Journal of Science and Technology


Indian Journal of Science and Technology

Year: 2021, Volume: 14, Issue: 33, Pages: 2646-2662

Original Article

A Comprehensive Review on Liquid-Liquid Extraction Based Systems in Treatment of Textile Wastewater

Received Date:12 June 2021, Accepted Date:20 September 2021, Published Date:11 October 2021


Objectives: To present an overview on various extraction systems used in treatment of textile wastewater. Methods: Google Scholar database was used to collect literature on liquid-liquid extraction systems in treatment of textile wastewater between 2000 and 2021. Findings: Even though a variety of methods are available for treatment of textile wastewater, certain methods remain neglected without much attention. One such method is liquid-liquid extraction-based systems. Hence, the manuscript presented an overview on applications of liquid-liquid extraction systems in treatment of textile wastewater. Novelty: Wastewater treatment is most important in today’s life because of excess urbanization and industrialization. In developing countries, tonnes of wastewater is discharged without prior treatment. Hence, liquidliquid extraction could be a novel method for treatment of textile wastewater.

Keywords: Wastewater; Liquidliquid extraction; Liquid membrane; Cloud point extraction; Reverse micellar extraction


  1. Sivamani S. Batch adsorption studies for chromium removal. Journal of environmental science & engineering. 2008;50(1):11–16. Available from: https://pubmed.ncbi.nlm.nih.gov/19192921/
  2. Sivamani S, Prasad BSN, Nithya K, Sivarajasekar N, Hosseini-Bandegharaei A. Back-propagation neural network: Box–Behnken design modelling for optimization of copper adsorption on orange zest biochar. International Journal of Environmental Science and Technology. 2021;p. 1–16. Available from: https://dx.doi.org/10.1007/s13762-021-03411-1
  3. Sivarajasekar N, Mohanraj N, Sivamani S, Maran JP, Moorthy IG, Balasubramani K. Statistical optimization studies on adsorption of ibuprofen onto Albizialebbeck seed pods activated carbon prepared using microwave irradiation. Materials Today: Proceedings. 2018;5(2):7264–7274. Available from: https://dx.doi.org/10.1016/j.matpr.2017.11.394
  4. Robinson T, McMullan G, Marchant R, Nigam P. Remediation of dyes in textile effluent: a critical review on current treatment technologies with a proposed alternative. Bioresource Technology. 2001;77(3):247–255. Available from: https://dx.doi.org/10.1016/s0960-8524(00)00080-8
  5. Marsousi S, Karimi-Sabet J, Moosavian MA, Amini Y. Liquid-liquid extraction of calcium using ionic liquids in spiral microfluidics. Chemical Engineering Journal. 2019;356:492–505. Available from: https://dx.doi.org/10.1016/j.cej.2018.09.030
  6. Mecha AC, Chollom MN. Photocatalytic ozonation of wastewater: a review. Environmental Chemistry Letters. 2020;18(5):1491–1507. Available from: https://dx.doi.org/10.1007/s10311-020-01020-x
  7. Parvathi C. Role of tapioca peel activated carbon (TPAC) in decolourisation of Red Brown C4R reactive dye. Indian Journal of Science and Technology. 2010;3(3):290–292. Available from: https://dx.doi.org/10.17485/ijst/2010/v3i3.14
  8. Muthuraman G, Teng TT. Extraction of methyl red from industrial wastewater using xylene as an extractant. Progress in Natural Science. 2009;19(10):1215–1220. Available from: https://dx.doi.org/10.1016/j.pnsc.2009.04.002
  9. Hajarabeevi N, Bilal IM, Easwaramoorthy D, Palanivelu K. Facilitated transport of cationic dyes through a supported liquid membrane with D2EHPA as carrier. Desalination. 2009;245(1-3):19–27. Available from: https://dx.doi.org/10.1016/j.desal.2008.06.009
  10. Pandit P, Basu S. Removal of Organic Dyes from Water by Liquid–Liquid Extraction Using Reverse Micelles. Journal of Colloid and Interface Science. 2002;245(1):208–214. Available from: https://dx.doi.org/10.1006/jcis.2001.7939
  11. Tatara E, Materna K, Schaadt A, Bart HJ, Szymanowski J. Cloud Point Extraction of Direct Yellow. Environmental Science & Technology. 2005;39(9):3110–3115. Available from: https://dx.doi.org/10.1021/es049381x
  12. Muthuraman G, Palanivelu K. Transport of textile anionic dyes using cationic carrier by bulk liquid membrane. Journal of Scientific and Industrial Research. 2005;64:529–533. Available from: http://nopr.niscair.res.in/bitstream/123456789/5162/1/JSIR%2064(7)%20529-533.pdf
  13. Kusumastuti A, Anis S, Syamwil R, Ahmad AL, , , et al. Emulsion Liquid Membrane for Textile Dyes Removal: Extraction Process. Journal of Physical Science. 2018;29(Supp. 2):175–184. Available from: https://dx.doi.org/10.21315/jps2018.29.s2.13
  14. Tarkwa JB, Oturan N, Acayanka E, Laminsi S, Oturan MA. Photo-Fenton oxidation of Orange G azo dye: process optimization and mineralization mechanism. Environmental Chemistry Letters. 2019;17(1):473–479. Available from: https://dx.doi.org/10.1007/s10311-018-0773-0
  15. Brezinski K, Gorczyca B, Sadrnourmohammadi M. Ion-exchange for trihalomethane control in potable water treatment – a municipal water treatment case study in Rainy River, Ontario, Canada. Water Quality Research Journal. 2019;54(2):142–160. Available from: https://dx.doi.org/10.2166/wqrj.2018.134
  16. Guo Q, Zhou C, Ma Z, Yang X. Fundamentals of TiO 2 Photocatalysis: Concepts, Mechanisms, and Challenges. Advanced Materials. 2019;31(50):1901997. Available from: https://doi.org/10.1002/adma.201901997
  17. Buthiyappan A, Raman AAA, Daud WMAW. Development of an advanced chemical oxidation wastewater treatment system for the batik industry in Malaysia. RSC Advances. 2016;6(30):25222–25241. Available from: https://dx.doi.org/10.1039/c5ra26775g
  18. Shahmansouri A, Bellona C. Nanofiltration technology in water treatment and reuse: applications and costs. Water Science and Technology. 2015;71(3):309–319. Available from: https://dx.doi.org/10.2166/wst.2015.015
  19. Antony FM, Pal D, Wasewar K. Separation of bio-products by liquid–liquid extraction. Physical Sciences Reviews. 2021;6(4). Available from: https://dx.doi.org/10.1515/psr-2018-0065
  20. Khraisheh M, AlMomani F, Inamdar M, Hassan MK, Al-Ghouti MA. Ionic liquids application for wastewater treatment and biofuel production: A mini review. Journal of Molecular Liquids. 2021;337:116421. Available from: https://dx.doi.org/10.1016/j.molliq.2021.116421
  21. Santana-Mayor Á, Socas-Rodríguez B, Rodríguez-Ramos R, Herrera-Herrera AV, Rodríguez-Delgado MÁ. Quality assessment of environmental water by a simple and fast non-ionic hydrophobic natural deep eutectic solvent-based extraction procedure combined with liquid chromatography tandem mass spectrometry for the determination of plastic migrants. Analytical and Bioanalytical Chemistry. 2021;413(7):1967–1981. Available from: https://dx.doi.org/10.1007/s00216-021-03166-1
  22. Rahi MN, Jaeel AJ, Abbas AJ. Treatment of petroleum refinery effluents and wastewater in Iraq: A mini review. IOP Conference Series: Materials Science and Engineering. 2021;1058(1):012072. Available from: https://dx.doi.org/10.1088/1757-899x/1058/1/012072
  23. Klemz AC, Weschenfelder SE, Neto SLdC, Damas MSP, Viviani JCT, Mazur LP, et al. Oilfield produced water treatment by liquid-liquid extraction: A review. Journal of Petroleum Science and Engineering. 2021;199:108282. Available from: https://dx.doi.org/10.1016/j.petrol.2020.108282
  24. Golcs Á, Bezúr L, Huszthy P, Tóth T. Liquid-liquid extraction and facilitated membrane transport of Pb2+ using a lipophilic acridono-crown ether as carrier. Journal of Inclusion Phenomena and Macrocyclic Chemistry. 2021;99(1-2):117–129. Available from: https://dx.doi.org/10.1007/s10847-020-01036-4
  25. Valley B, Jing B, Ferreira M, Zhu Y. Rapid and Efficient Coacervate Extraction of Cationic Industrial Dyes from Wastewater. ACS Applied Materials & Interfaces. 2019;11(7):7472–7478. Available from: https://dx.doi.org/10.1021/acsami.8b21674
  26. Ferreira AM, Coutinho JAP, Fernandes AM, Freire MG. Complete removal of textile dyes from aqueous media using ionic-liquid-based aqueous two-phase systems. Separation and Purification Technology. 2014;128:58–66. Available from: https://dx.doi.org/10.1016/j.seppur.2014.02.036
  27. Othman N, Aziz NSNM, Harruddin N. Reactive Dye Removal from Simulated Wastewater using Tetrabutyl Ammonium Bromide as an Extractant. Jurnal Teknologi. 2014;67(2):67. Available from: https://dx.doi.org/10.11113/jt.v67.2736
  28. Soniya M, Muthuraman G. Recovery of methylene blue from aqueous solution by liquid–liquid extraction. Desalination and Water Treatment. 2015;53(9):2501–2509. Available from: https://doi.org/10.1080/19443994.2013.866055
  29. Elumalai S, Muthuraman G. Removal and Recovery of Methyl Violet Dye from Industrial Wastewater by Liquid–Liquid Extraction. In: Singh V, Yadav S, Yadava R., eds. Water Quality Management. Water Science and Technology Library. (Vol. 79, pp. 231-240) Springer Singapore. 2018.
  30. Muthuraman G, Teng TT, Tan SH. Liquid–liquid extraction of Cibacron Red FN-R by TBAB as an extractant. Desalination. 2012;284:135–141. Available from: https://dx.doi.org/10.1016/j.desal.2011.08.047
  31. Muthuraman G, Teng TT, Leh CP, Norli I. Extraction and recovery of methylene blue from industrial wastewater using benzoic acid as an extractant. Journal of Hazardous Materials. 2009;163(1):363–369. Available from: https://dx.doi.org/10.1016/j.jhazmat.2008.06.122
  32. Muthuraman G, Palanivelu K. Transport of textile dye in vegetable oils based supported liquid membrane. Dyes and Pigments. 2006;70(2):99–104. Available from: https://dx.doi.org/10.1016/j.dyepig.2005.05.002
  33. Muthuraman G, Palanivelu K. Removal and recovery of low salt dye golden yellow LS by liquid-liquid extraction. Indian Journal of Chemical Technology. 2004;11(2):166–169. Available from: http://nopr.niscair.res.in/bitstream/123456789/16773/1/IJCT%2011%282%29%20166-169.pdf
  34. Othman N, Mili N, Wong YM. Liquid-liquid Extraction of Black B Dye from Liquid Waste Solution Using Tridodecylamine. Journal of Environmental Science and Technology. 2011;4(3):324–331. Available from: https://dx.doi.org/10.3923/jest.2011.324.331
  35. Elumalai S, Muthuraman G, Sathya M, Soniya M, Teng TT. Recovery of dye from textile effluents using phenol as an extractant. Journal of Industrial and Engineering Chemistry. 2014;20(4):1958–1964. Available from: https://dx.doi.org/10.1016/j.jiec.2013.09.017
  36. Xu J, Duan W, Zhou X, Zhou J. Extraction of phenol in wastewater with annular centrifugal contactors. Journal of Hazardous Materials. 2006;131(1-3):98–102. Available from: https://dx.doi.org/10.1016/j.jhazmat.2005.09.011
  37. Hu H, Yang M, Dang J. Treatment of strong acid dye wastewater by solvent extraction. Separation and Purification Technology. 2005;42(2):129–136. Available from: https://dx.doi.org/10.1016/j.seppur.2004.07.002
  38. Vijayaraghavan R, Vedaraman N, Surianarayanan M, MacFarlane DR. Extraction and recovery of azo dyes into an ionic liquid. Talanta. 2006;69(5):1059–1062. Available from: https://dx.doi.org/10.1016/j.talanta.2005.12.042
  39. Raghavarao KSMS, Ranganathan TV, Srinivas ND, Barhate RS. Aqueous two phase extraction?an environmentally benign technique. Clean Technologies and Environmental Policy. 2003;5:136–141. Available from: https://dx.doi.org/10.1007/s10098-003-0193-z
  40. Al-Degs YS, Abu-Surrah AS, Ibrahim KA. Preparation of highly selective solid-phase extractants for Cibacron reactive dyes using molecularly imprinted polymers. Analytical and Bioanalytical Chemistry. 2009;393(3):1055–1062. Available from: https://dx.doi.org/10.1007/s00216-008-2502-1
  41. Chen HL, Wei GT. The Use Ionic Liquid as the Eluent Additive for HPLC Separation of Ionic Dyes. Journal of the Chinese Chemical Society. 2010;57(4B):836–843. Available from: https://dx.doi.org/10.1002/jccs.201000116
  42. Sonune A, Ghate R. Developments in wastewater treatment methods. Desalination. 2004;167:55–63. Available from: https://dx.doi.org/10.1016/j.desal.2004.06.113
  43. Sivarajasekar N, Ramasubbu S, Maran JP, Priya B. Cationic Dyes Sequestration from Aqueous Phase Using Biosurfactant Based Reverse Micelles. In: Recent Advances in Chemical Engineering. (pp. 67-74) Springer Singapore. 2016.
  44. Subashini R, Sivarajasekar N, Balasubramani K, Prakashmaran J. Saponin-Aided Reverse Micellar Extraction of Malachite Green Dye From Aqueous Solutions. In: Lecture Notes on Multidisciplinary Industrial Engineering. (pp. 89-97) Springer Singapore. 2020.
  45. Sawada K, Ueda M. Enzyme processing of textiles in reverse micellar solution. Journal of Biotechnology. 2001;89(2-3):263–269. Available from: https://dx.doi.org/10.1016/s0168-1656(01)00310-8
  46. Sowmya R, Sivarajasekar N, Manimaran DR, Sivamani S. Biosurfactant assisted liquid-membrane extraction of methyl-orange from aqueous solutions. AIP Conference Proceedings. 2020;2270:20008. Available from: https://doi.org/10.1063/5.0019525
  47. Tang AYL, Lee CH, Wang YM, Kan CW. Reverse Micellar Dyeing of Cotton Fiber with Reactive Dyes: A Study of the Effect of Water pH and Hardness. ACS Omega. 2019;4(7):11808–11814. Available from: https://dx.doi.org/10.1021/acsomega.9b00597
  48. Wang Y, Tang Yl, Lee Ch, Kan Cw. Reverse Micellar Dyeing of Wool Fabric with Reactive Dyes. Fibers and Polymers. 2019;20(11):2367–2375. Available from: https://dx.doi.org/10.1007/s12221-019-9423-9
  49. Bukman L, Fernandes-Machado NRC, Caetano W, Tessaro AL, Hioka N. Treatment of wastewater contaminated with ionic dyes: Liquid-liquid extraction induced by reversed micelle followed by photodegradation. Separation and Purification Technology. 2017;189:162–169. Available from: https://dx.doi.org/10.1016/j.seppur.2017.08.004
  50. Ueda AC, Oliveira LHd, Hioka N, Aznar M. Liquid−Liquid Extraction of Basic Yellow 28, Basic Blue 41, and Basic Red 46 Dyes from Aqueous Solutions with Reverse Micelles. Journal of Chemical & Engineering Data. 2011;56(3):652–657. Available from: https://dx.doi.org/10.1021/je1008558
  51. Pandit P, Basu S. Dye and Solvent Recovery in Solvent Extraction Using Reverse Micelles for the Removal of Ionic Dyes. Industrial & Engineering Chemistry Research. 2004;43(24):7861–7864. Available from: https://dx.doi.org/10.1021/ie0402160
  52. Pandit P, Basu S. Removal of Ionic Dyes from Water by Solvent Extraction Using Reverse Micelles. Environmental Science & Technology. 2004;38(8):2435–2442. Available from: https://dx.doi.org/10.1021/es030573m
  53. Noritomi H, Tamai S, Saito H, Kato S. Extraction of water miscible organic dyes by reverse micelles of alkyl glucosides. Colloid and Polymer Science. 2009;287(4):455–459. Available from: https://dx.doi.org/10.1007/s00396-008-1988-6
  54. Feitosa E, Catelam KT, Hasmann FA, Johansson HO, Roberto IC, Pessoa A. Phase diagrams of a CTAB/organic solvent/buffer system applied to extraction of enzymes by reverse micelles. Journal of Chromatography B. 2008;862(1-2):58–63. Available from: https://dx.doi.org/10.1016/j.jchromb.2007.10.046
  55. Noorashikin MS, Sohaimi NM, Suda N, Aziz HZ, Zaini SRM, Kandasamy S, et al. The application of cloud point extraction in environmental analysis. Journal of Sustainability Science and Management. 2017;12(1):79–95. Available from: https://soe.umt.edu.my/wp-content/uploads/sites/51/2017/06/9-web.pdf
  56. Purkait MK, Vijay SS, DasGupta S, De S. Separation of congo red by surfactant mediated cloud point extraction. Dyes and Pigments. 2004;63(2):151–159. Available from: https://dx.doi.org/10.1016/j.dyepig.2004.01.010
  57. Duran C, Ozdes D, Bulut VN, Tufekcī M, Soylak M. Cloud-Point Extraction of Rhodamine 6G by Using Triton X-100 as the Non-Ionic Surfactant. Journal of AOAC International. 2011;94(1):286–292. Available from: https://dx.doi.org/10.1093/jaoac/94.1.286
  58. Arunagiri A, Kalaichelvi P, Cherukuri S, Vijayan A. Studies on removal of reactive blue dye using cloud point extraction. International journal of chemical & environmental engineering. 2012;3(1):16–23. Available from: https://www.researchgate.net/publication/285135842_Studies_on_removal_of_Reactive_Blue_dye_using_cloud_point_extraction
  59. Mazzola PG, Lopes AM, Hasmann FA, Jozala AF, Penna TC, Magalhaes PO, et al. Liquid–liquid extraction of biomolecules: an overview and update of the main techniques. Journal of Chemical Technology & Biotechnology. 2008;83(2):143–157. Available from: https://dx.doi.org/10.1002/jctb.1794
  60. Kamiński W, Kwapiński W. Applicability of liquid membranes in environmental protection. Polish Journal of environmental studies. 2000;9(1):37–43. Available from: http://www.pjoes.com/Applicability-of-Liquid-Membranes-in-Environmental-Protection,87274,0,2.html
  61. Muthuraman G, Palanivelu K, Teng TT. Transport of cationic dye by supported liquid membrane using D2EHPA as the carrier. Coloration Technology. 2010;126(2):97–102. Available from: https://dx.doi.org/10.1111/j.1478-4408.2010.00233.x
  62. Memon FN, Memon S, Minhas FT. Rapid transfer of methyl red using calix[6]arene as a carrier in a bulk liquid membrane. Comptes Rendus Chimie. 2014;17(6):577–585. Available from: https://dx.doi.org/10.1016/j.crci.2013.09.015
  63. Montero GA, Smith CB, Hendrix WA, Butcher DL. Supercritical Fluid Technology in Textile Processing:  An Overview. Industrial & Engineering Chemistry Research. 2000;39(12):4806–4812. Available from: https://dx.doi.org/10.1021/ie0002475
  64. Santos WLF, Porto MF, Muniz EC, Povh NP, Rubira AF. Incorporation of disperse dye in N,N-dimethylacrylamide modified poly(ethylene terephthalate) fibers with supercritical CO2. The Journal of Supercritical Fluids. 2001;19(2):177–185. Available from: https://dx.doi.org/10.1016/s0896-8446(00)00083-8
  65. Abbasi A, Seifollahi Z, Rahbar-Kelishami A. Experimental work on decontamination of wastewaters containing organic dye by liquid phase micro extraction method. Separation Science and Technology. 2021;56(6):1047–1059. Available from: https://dx.doi.org/10.1080/01496395.2020.1751201
  66. Kaur P, Rajani N, Kumawat P, Singh N, Kushwaha JP. Performance and mechanism of dye extraction from aqueous solution using synthesized deep eutectic solvents. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2018;539:85–91. Available from: https://dx.doi.org/10.1016/j.colsurfa.2017.12.013
  67. Gharehbaghi M, Shemirani F. A Novel Method for Dye Removal: Ionic Liquid-Based Dispersive Liquid-Liquid Extraction (IL-DLLE) CLEAN - Soil, Air, Water. 2012;40(3):290–297. Available from: https://dx.doi.org/10.1002/clen.201100258
  68. Mahmoud AS, Ghaly AE, Brooks MS. Removal of Dye from Textile Wastewater Using Plant Oils Under Different pH and Temperature Conditions. American Journal of Environmental Sciences. 2007;3(4):205–218. Available from: https://dx.doi.org/10.3844/ajessp.2007.205.218


© 2021 Sivamani et al. This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited. Published By Indian Society for Education and Environment (iSee)


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