• P-ISSN 0974-6846 E-ISSN 0974-5645

Indian Journal of Science and Technology

Article

Indian Journal of Science and Technology

Year: 2022, Volume: 15, Issue: 39, Pages: 1997-2003

Original Article

Ni-Mn-Al Heusler Alloy Samples Preparation by Mechanical Alloying Method and Study of their Investigated Properties

Received Date:19 April 2022, Accepted Date:12 September 2022, Published Date:17 October 2022

Abstract

Objective: In this work, ternary Ni-Mn-Al Heusler alloy powder samples were fabricated using mechanical alloying technique to study its alloy formation mechanism and the effects of mechanical alloying on the investigated properties. Methods: The samples were prepared using high energy planetary ball mill under argon conditions. The milling time of 0 h (hour/hours), 5 h, 10 h and 15 h were selected to see the progress of alloy formation. The microstructural, compositional, thermal and magnetic studies of ball milled powder samples were conducted. Findings: Compositional study reveals stoichiometric Heusler composition (X2YZ) of Ni-Mn-Al alloy with no contamination. The optimum milling time required for the formation of alloy by mechanical alloying resulted through the proper selection of milling parameters. The average crystallite size obtained reveals that nanocrystalline structure of Ni-Mn-Al alloy was achieved during the ball milling operation. The successive heating of powder particles in differential scanning calorimetry showed crystallization and alloy formation. Novelty/Applications: The magnetic study indicated soft ferromagnetic nature of the selected ball milled powder sample suggesting the alloy can be developed for possible ferromagnetic shape memory alloy applications.

Keywords: Ni-Mn-Al; Heusler alloy; Mechanical alloying; Ball milling; Structural properties

References

  1. Everhart W, Newkirk J. Mechanical properties of Heusler alloys. Heliyon. 2019;5(5):e01578. Available from: https://doi.org/10.1016/j.heliyon.2019.e01578
  2. Bachaga T, Zhang &M, Khitouni JJ, Sunol. NiMn-based Heusler magnetic shape memory alloys: a review. The International Journal of Advanced Manufacturing Technology. 2019;p. e01578. Available from: https://doi.org/10.1007/s00170-019-03534-3
  3. Singh S. Properties of Ni-Mn based Heusler Alloys with Martensitic Transition. University of Calcutta. 2014;p. 1–182.
  4. Lyange MV, Barmina ES, Khovaylo VV. Structural and Magnetic Properties of Ni-Mn-Al Heusler Alloys: A Review. Materials Science Foundations. 2015;81-82:232–242. Available from: https://doi.org/10.4028/www.scientific.net/MSFo.81-82.232
  5. Moya X, Mañosa L, Planes A, Krenke T, Acet M, Wassermann EF. Martensitic transition and magnetic properties in Ni–Mn–X alloys. Materials Science and Engineering: A. 2006;438-440(440):911–915. Available from: http:doi.org/10.1016/j,mesa.2006.02.053
  6. Dhanal SV, Ghaste A, Akkimardi VG, Kori SA, Bhosale CH. Synthesis and structural studies of Ni-Mn based Heusler shape memory alloys. AIP Conference Proceedings. 2019;2162. Available from: https://doi.org/10.1063/1.5130212
  7. Dhanal SV, Ghaste A, Akkimardi VG, Kori SA. Study of the effect of mechanical alloying on the structure of Ni-Mn-Sn Heusler alloy. Journal of Mechanical Science and Technology. 2020;34(1):149–154. Available from: https://doi.org/10.1007/s12206-019-1216-y
  8. Saini D, Singh S, Banerjee MK, Sachdev K. Study of Structural Evolution and Magnetic Behavior of Ni50Mn45Sn5 Alloy. Journal of Nano- and Electronic Physics. 2017;9(3):03025-1-03025-5. Available from: https://doi.org/10.21272/jnep.9(3).03025
  9. Vaidya M, Muralikrishna GM, Murty BS. High-entropy alloys by mechanical alloying: A review. Journal of Materials Research. 2019;34(5):664–686. Available from: https://doi.org/10.1557/jmr.2019.37
  10. Elsayed A, Ibrahim R, Bahlol M, Dawood O. Synthesis of Cu-Ni-Al shape memory alloys by powder metallurgy. Materials Science Forum. 2018;941:1618–1622. Available from: https://doi.org/10.34133/2019/4219812
  11. Cullity BD, Weymouth JW. Elements of X-Ray Diffraction. American Journal of Physics. 1957;25(6):394–395.
  12. Suryanarayana C. Mechanical alloying and milling. Progress in Materials Science. 2001;46:10–19. Available from: https://doi.org/10.1016/S0079-6425(99)00010-9
  13. Fujita A, Fukamichi K, Gejima F, Kainuma R, Ishida K. Magnetic properties and large magnetic-field-induced strains in off-stoichiometric Ni–Mn–Al Heusler alloys. Applied Physics Letters. 2000;77(19):3054–3056. Available from: http://dx.doi.org/10.1063/1.1323552
  14. Nirmala B, Vallal PK, Amuthan R, Mahendran M, Nanoscience N. Nanoscience and Nanotechnology. 2011;1:8–13. Available from: https://doi.org10.5923/j.nn.20110101.02

Copyright

© 2022 Dhanal et al. This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited. Published By Indian Society for Education and Environment (iSee)

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