• P-ISSN 0974-6846 E-ISSN 0974-5645

Indian Journal of Science and Technology

Article

Indian Journal of Science and Technology

Year: 2021, Volume: 14, Issue: 31, Pages: 2526-2534

Original Article

Study of Physical, Mechanical, and Barrier Properties in Linear Low-Density Polyethylene Mixed with Silver Zeolite Nanoparticles (Ag-zeolite) Film

Received Date:01 January 2021, Accepted Date:28 April 2021, Published Date:18 September 2021

Abstract

Background/Objectives: The primary goal of using active packaging is to extend the shelf life of products inside the package. This research aimed to study the properties of LLDPE with Ag-zeolite nanoparticles to extend product shelf-life. Methods/Statistical analysis: In this research, LLDPE films combined with Ag-zeolite at 0.5 and 1 % wt. were produced by using a twinscrew extruder and a blown film extruder. The inspected properties included the physical properties, the mechanical properties, and the barrier properties. The data were analyzed by performing the one-way ANOVA analysis and paired comparison analysis, using the IBM SPSS software with the confidential statistics of 95%. Findings: The analyzed physical properties of the plastic films in this study showed that, when Ag-zeolite was added to the LLDPE, the yellowness index of the film increased. When Ag-zeolite was added to LLDPE plastic films, it did not appear to alter the tested plastics’ melting temperature (Tm), crystallization temperature (Tc), or the crystallinity of all the plastic films and conformed to the FT-TR and XRD curves. Ag- zeolite agent’s dispersion on the film’s gloss seemed to be aligned with the SEM images. However, although adding an Ag-zeolite agent into LLDPE film contributed to the change in color, it did not affect the polymer’s characteristics and structure. Lastly, the mechanical properties across the LLDPE plastic films mixed with Ag-zeolite agent statistically significantly decreased, but the barrier properties of the films did not change. Applications: The study results could be an alternative for manufacturing active packaging. Novelty: Color changing of LLDPE film mixed with Ag-zeolite agent, but it did not change the polymer’s characteristic or structure.

Keywords: Antibacterial agent; Linear lowdensity polyethylene (LLDPE); Physical properties; Plastic film; Silver zeolite nanoparticles (Ag-zeolite); Yellowness index

References

  1. Birley AW. Plastics materials: properties and applications. Springer Science and Business Media. 2012.
  2. Dennis C, Stringer M. Chilled foods: a comprehensive guide. Ellis Horwood. 1992.
  3. Panrong T, Karbowiak T, Harnkarnsujarit N. Thermoplastic starch and green tea blends with LLDPE films for active packaging of meat and oil-based products. Food Packaging and Shelf Life. 2019;21:100331. Available from: https://dx.doi.org/10.1016/j.fpsl.2019.100331
  4. Brody A, Strupinsky E, Kline L. Active packaging for food applications. CRC press. 2001.
  5. Dutta P, Wang B. Zeolite-supported silver as antimicrobial agents. Coordination Chemistry Reviews. 2019;383:1–29. Available from: https://dx.doi.org/ 10.1016/j.ccr.2018.12.014
  6. Le A, Dang V, Nguyen N, Vu C, Nguyen Q. Preparation of polypropylene/silver nano-zeolite plastics and evaluation of antibacterial and mechanical properties. International Journal of Composite Materials. 2016;6(4):89–94. doi: 10.5923/j.cmaterials.20160604.01
  7. Carbone M, Donia DT, Sabbatella G, Antiochia R. Silver nanoparticles in polymeric matrices for fresh food packaging. Journal of King Saud University - Science. 2016;28(4):273–279. Available from: https://dx.doi.org/10.1016/j.jksus.2016.05.004
  8. Shameli K, Ahmad M, Mohsen Z, Yunis WZ, Ibrahim NA. Fabrication of silver nanoparticles doped in the zeolite framework and antibacterial activity. International Journal of Nanomedicine. 2011;6(331). Available from: https://dx.doi.org/10.2147/ijn.s16964
  9. Kuehni RG. Color: An introduction to practice and principles. John Wiley & Sons. 2012.
  10. Boschetto DL, Lerin L, Cansian R, Pergher S, Luccio MD. Preparation and antimicrobial activity of polyethylene composite films with silver exchanged zeolite-Y. Chemical Engineering Journal. 2012;204:210–216. Available from: https://dx.doi.org/10.1016/j.cej.2012.07.111
  11. Morones JR, Elechiguerra JL, Camacho A, Holt K, Kouri JB, Ramírez JT. The bactericidal effect of silver nanoparticles. Nanotechnology. 2005;16(10):2346–2353. Available from: https://dx.doi.org/10.1088/0957-4484/16/10/059
  12. Kundu PP, Biswas J, Kim H, Shim SE, Choe S, Lee DS. Effect of calcite and calcite/zeolite hybrid fillers on LLDPE and PP composites. Advances in Polymer Technology. 2004;23(3):230–238. Available from: https://dx.doi.org/10.1002/adv.20013
  13. Ray SS, Okamoto M. Polymer/layered silicate nanocomposites: a review from preparation to processing. Progress in Polymer Science. 2003;28:1539–1641. Available from: https://dx.doi.org/10.1016/j.progpoly msci.2003.08.002
  14. Leong YW, Bakar M, Ishak Z, Ariffin A, Pukanszky B. Comparison of the mechanical properties and interfacial interactions between talc, kaolin, and calcium carbonate filled polypropylene composites. Journal of Applied Polymer Science. 2004;91(5):3315–3326. Available from: https://dx.doi.org/10.1002/app.13542
  15. Basalp D, Tihminlioğlu F. The effects of natural zeolite and silane coupling agents on melting and crystallization behaviour of polypropylene. Journal of Thermal Analysis and Calorimetry. 2008;94(3):757–765. Available from: https://dx.doi.org/10.1007/s10973-008-9367-6
  16. Mihindukulasuriya SDF, Lim LT. Nanotechnology development in food packaging: A review. Trends in Food Science & Technology. 2014;40(2). Available from: https://doi.org/10.1016/j.tifs.2014.09.009
  17. Zampino D, Ferreri T, Puglisi C, Mancuso M, Zaccone R, Scaffaro R. PVC silver zeolite composites with antimicrobial properties. Journal of Materials Science. 2011;46(20):6734–6743. Available from: https://dx.doi.org/10.1007/s10853-011-5629-y
  18. Kim D, Thanakkasaranee S, Seo J, Khan SB. Effect of porous zeolite on temperature-dependent physical properties of polypropylene/octadecane (PP/OD) composite films. Express Polymer Letters. 2018;12(7):658–674. Available from: https://dx.doi.org/10.3144/expresspolymlett.2018.56

Copyright

© 2021 Muangprakaew et al. This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited. Published By Indian Society for Education and Environment (iSee)

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