Synthesis and spectral investigation of some Zn (II), Hg (II), Co (II) and Cu (II) Schiff base complexes

A  Rahmani; E  Mahmoodabadi; B  Heidari; M  Montazerozohori   and S  Joohari

doi:10.17485/ijst/2011/v4i11.4

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Synthesis and spectral investigation of some Zn (II), Hg (II), Co (II) and Cu (II) Schiff base complexes

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Indian Journal of Science and Technology

DOI: 10.17485/ijst/2011/v4i11.4

Year: 2011, Volume: 4, Issue: 11, Pages: 1402-1406

Original Article

Synthesis and spectral investigation of some Zn (II), Hg (II), Co (II) and Cu (II) Schiff base complexes

A. Rahmani¹ , E. Mahmoodabadi¹ , B. Heidari¹ , M. Montazerozohori^*2 and S. Joohari²

¹ Department of Chemistry, Firoozabad Branch, Islamic Azad University, Firoozabad, Iran
² Department of Basic Sciences, Yasouj Branch, Islamic Azad University, Yasouj, Iran
[email protected]

This work is licensed under a Creative Commons Attribution 4.0 International License.

Abstract

Three symmetrical Schiff base ligands of N, N′-bis (2-chlorobenzylidene) ethane-1, 2-diamine (BCBEN), N,N′-bis (2- nitrobenzylidene) ethane-1,2-diamine and N,N'-bis (3-phenylallylidene)-o-phenylenediamine and some zinc (II), mercury (II), cobalt (II) and copper (II) complexes were synthesized and characterized by elemental analyses, ¹H NMR, ¹³C NMR, FT-IR, UV-Visible spectra, and molar conductance. All compounds were found to be non-electrolytes in the dimethylsulfoxide solutions.
Keywords: Schiff base complex, Thiocyanate, Spectral, Symmetrical.