Synthesis, Characterization and Corrosion Inhibition study of N-(4-((4-(pyridin-2-yl) piperazin-1-yl) methyl) phenyl) quinoline-6-carboxamide on Mild Steel under HCl Solution

S Anbalagan; M Ravishankar; S Sivakumar; M Sivakumar; E Krishna

doi:10.17485/IJST/v16i11.2364

Article

Synthesis, Characterization and Corrosion Inhibition study of N-(4-((4-(pyridin-2-yl) piperazin-1-yl) methyl) phenyl) quinoline-6-carboxamide on Mild Steel under HCl Solution

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Indian Journal of Science and Technology

DOI: 10.17485/IJST/v16i11.2364

Year: 2023, Volume: 16, Issue: 11, Pages: 803-815

Original Article

Synthesis, Characterization and Corrosion Inhibition study of N-(4-((4-(pyridin-2-yl) piperazin-1-yl) methyl) phenyl) quinoline-6-carboxamide on Mild Steel under HCl Solution

S Anbalagan^1,2, M Ravishankar^1*, S Sivakumar³, M Sivakumar³, E Krishna⁴

¹Department of Chemistry, Rajah Serfoji Government College, Affiliated to Bharathidhasan University, Thanjur, Tamil Nadu, India
²Department of Chemistry, Laxminarayana College of Arts & Science (women), Dharmapuri, Tamil Nadu, India
³Department of Chemistry, E. R. K Arts and Science College, Dharmapuri, Tamil Nadu, India
⁴Department of Chemistry, P.S.A Arts and Science College, Dharmapuri, Tamil Nadu, India

*Corresponding Author
Email: [email protected]

Received Date:08 December 2022, Accepted Date:27 January 2023, Published Date:15 March 2023

This work is licensed under a Creative Commons Attribution 4.0 International License.

Abstract

Objectives: To use the newly synthesized efficient organic corrosion inhibitor N-(4-((4-(pyridin-2-yl) piperazin-1-yl)methyl)phenyl)quinoline-6-carboxamide to carry out on mild steel corrosion inhibition study. Methods: N-(4-((4-(pyridin- 2-yl)piperazin-1-yl)methyl)phenyl)quinoline-6-carboxamide was synthesized by stirring method under 0oC to room temperature at 12 hrs. The synthesized organic inhibitor was characterized by 1H NMR, 13C NMR, UV and FTIR spectroscopy. The inhibition effect of organic inhibitor on the mild steel corrosion was investigated with weight loss measurement by gold measuring weighing balance. The inhibitor anchored down on the mild steel surface was analyzed by scanning electron microscopy and Atomic Force Microscopy. Findings: The inhibitor shows a better inhibition efficiency of maximum 74.41% in 1N HCl medium. In addition to this adsorption isothermal models were also interpreted to fit the adsorption behavior of the inhibitor compound on mild steel surface. Thus, the result shows the Langmuir adsorption isotherm. As a result, the interactions between inhibitor and mild steel surface have chemisorptions. Novelty: The N-(4-((4-(pyridin-2-yl) piperazin-1-yl)methyl)phenyl)quinoline-6-carboxamide shows better corrosion inhibition efficiency (74.41%). In addition, inhibitor and mild steel surface show chemisorptions interaction, which confirms free energy and enthalpy of adsorption.

Keywords: Carbaxamide Derivative; Scanning Electronic Microscopy; Atomic Force Microscopy Weight Loss Measurement And NMR

References

Omran MA, Fawzy M, Mahmoud AED, Abdullatef OA. Optimization of mild steel corrosion inhibition by water hyacinth and common reed extracts in acid media using factorial experimental design. Green Chemistry Letters and Reviews. 2022;15(1):216–232. Available from: https://doi.org/10.1080/17518253.2022.2032844
Salmasifar A, Edraki M, Alibakhshi E, Ramezanzadeh B, Bahlakeh G. Combined electrochemical/surface investigations and computer modeling of the aquatic Artichoke extract molecules corrosion inhibition properties on the mild steel surface immersed in the acidic medium. Journal of Molecular Liquids. 2021;327:114856. Available from: https://doi.org/10.1016/j.molliq.2020.114856
Kumar H, Yadav V, Anu, Saha SK, Kang N. Adsorption and inhibition mechanism of efficient and environment friendly corrosion inhibitor for mild steel: Experimental and theoretical study. Journal of Molecular Liquids. 2021;338:116634. Available from: https://doi.org/10.1016/j.molliq.2021.116634
Wu Y, Guo L, Tan B, Li W, Zhang F, Zheng X. 5-Mercapto-1-phenyltetrazole as a high-efficiency corrosion inhibitor for Q235 steel in acidic environment. Journal of Molecular Liquids. 2021;325:115132. Available from: https://doi.org/10.1016/j.molliq.2020.115132
Sheetal, Batra R, Singh AK, Singh M, Thakur S, Pani B, et al. Advancement of corrosion inhibitor system through N-heterocyclic compounds: a review. Corrosion Engineering, Science and Technology. 2023;58(1):73–101. Available from: https://doi.org/10.1080/1478422X.2022.2137979
Ashassi-Sorkhabi H, Kazempour A, Frouzat Z. Superior potentials of hydrazone Schiff bases for efficient corrosion protection of mild steel in 1.0 M HCl. Journal of Adhesion Science and Technology. 2021;35(2):164–184. Available from: https://doi.org/10.1080/01694243.2020.1794357
Kaabi I, Douadi T, Daoud D, Issaadi S, Sibous L, Chafaa S. Synthesis, characterization and anti-corrosion properties of two new Schiff bases derived from diamino diphenyl ether on carbon steel X48 in 1M HCl. Journal of Adhesion Science and Technology. 2021;35(6):559–589. Available from: https://doi.org/10.1080/01694243.2020.1816777
Alamiery AA. Investigations on Corrosion Inhibitory Effect of Newly Quinoline Derivative on Mild Steel in HCl Solution Complemented with Antibacterial Studies. Biointerface Research in Applied Chemistry. 2022;12(2):1561–1568. Available from: https://doi.org/10.33263/BRIAC122.15611568
Al-Amiery AA, Shaker LM. Corrosion inhibition of mild steel using novel pyridine derivative in 1 M hydrochloric acid. Koroze a ochrana materialu. 2020;64(2):59–64. Available from: https://doi.org/10.2478/kom-2020-0009
Chen Y, Chen Z, Zhuo YZ. Newly Synthesized Morpholinyl Mannich Bases as Corrosion Inhibitors for N80 Steel in Acid Environment. Materials. 2022;15(12):4218. Available from: https://doi.org/10.3390/ma15124218
Sami MB, Munakhethier A, Khudhair M, M, Khalid W, Mahdi A, et al. Corrosion Inhibition of Mild Steel in Hydrochloric Acid Environment Using Terephthaldehyde Based on Schiff Base: Gravimetric, Thermodynamic, and Computational Studies. Molecules. 2022;27. Available from: https://doi.org/10.3390/ molecules27154857
Alrebh A, Rammal MB, Omanovic S. A pyridine derivative 2-(2-Methylaminoethyl)pyridine (MAEP) as a ‘green’ corrosion inhibitor for low-carbon steel in hydrochloric acid media. Journal of Molecular Structure. 2021;1238:130333. Available from: https://doi.org/10.1016/j.molstruc.2021.130333
Mishra A, Aslam J, Verma C, Quraishi MA, Ebenso EE. Imidazoles as highly effective heterocyclic corrosion inhibitors for metals and alloys in aqueous electrolytes: A review. Journal of the Taiwan Institute of Chemical Engineers. 2020;114:341–358. Available from: https://doi.org/10.1016/j.jtice.2020.08.034
Yeestdev D, Dakeshwar KV, Elyor B, Rajesh H, Mamtatripathi OD, Kumar V, et al. N-hydroxypyrazine-2-carboxamide as a new and green corrosion inhibitor for mild steel in acidic medium: experimental, surface morphological and theoretical approach. Journal of Adhesion Science and Technology. 2022. Available from: https://doi.org/10.1080/01694243.2022.2068884
Sehmi A, Ouici HB, Guendouzi A, Ferhat M, Benali O, Boudjellal F. Corrosion Inhibition of Mild Steel by newly Synthesized Pyrazole Carboxamide Derivatives in HCl Acid Medium: Experimental and Theoretical Studies. Journal of The Electrochemical Society. 2020;167(15):155508. Available from: https://doi.org/10.1149/1945-7111/abab25
Ramachandran A, Anitha P, Gnanavel S. Structural and electronic impacts on corrosion inhibition activity of novel heterocyclic carboxamides derivatives on mild steel in 1 M HCl environment: Experimental and theoretical approaches. Journal of Molecular Liquids. 2022;359:119218. Available from: https://doi.org/10.1016/j.molliq.2022.119218
Ranjith PK, Ignatious A, Panicker CY, Sureshkumar B, Armakovic S, Armakovic SJ, et al. Spectroscopic investigations, DFT calculations, molecular docking and MD simulations of 3-[(4-Carboxyphenyl) carbamoyl]-4-hydroxy-2-oxo-1, 2-dihydroxy quinoline-6-carboxylic acid. Journal of Molecular Structure. 2022;1264(15):133315. Available from: https://doi.org/10.1016/j.molstruc.2022.133315
Yuhaoc Z, Yaowen Z. Newly Synthesized MorpholinylMannich Bases as Corrosion Inhibitors for N80 Steel in Acid. Environment. 2022;15:4218–4219. Available from: https://doi.org/10.3390/ma15124218
Bhawna C, Singh AK, Sanjeeve T, Balaram P, Hassane L, Ill-Min C, et al. Comparative Investigation of Corrosion-Mitigating Behavior of Thiadiazole-Derived Bis-Schiﬀ Bases for Mild Steel in Acid Medium:Experimental, Theoretical, and Surface Study. ACS Omega . 2020;5:13503. Available from: https://doi.org/10.1021/acsomega.9b04274
Senthilkumar G, Umarani C, Ramachandran A. Investigation on corrosion inhibition effect of N-[4-(1,3-benzo[d]thiazol-2-ylcarbamoyl)phenyl]quinoline-6-carboxamide as a novel organic inhibitor on mild steel in 1N HCl at different temperatures: Experimental and theoretical study. Journal of the Indian Chemical Society. 2021;98(6):100079. Available from: https://doi.org/10.1016/j.jics.2021.100079
Zhang X, Zhang M, Zhang Z, Li Q, Lv R, Wu W. Bis-Mannich bases as effective corrosion inhibitors for N80 steel in 15% HCl medium. Journal of Molecular Liquids. 2022;347:117957. Available from: https://doi.org/10.1016/j.molliq.2021.117957
Senthilkumar G, Umarani C, Ramachandran A. Synthesis of Novel corrosion Inhibitor N- (1,3-Benzothiazole-2yl) 4-Aminobenzamide in 1 Hydrochloric acid Medium. Asian Journal of chemistry. 2021;33(3):622–626. Available from: https://doi.org/10.14233/ajchem.2021.23042
Praveen BM, Prasanna BM, Mallikarjuna NM, Jagadeesh MR, Hebbar N, Rashmi D. Investigation of anticorrosive behaviour of novel tert-butyl 4-[(4-methyl phenyl) carbonyl] piperazine-1-carboxylate for carbon steel in 1M HCl. Heliyon. 2021;7(2):e06090. Available from: https://doi.org/10.1016/j.heliyon.2021.e06090
Kumarm R, Mahendray, Obot I. Electrochemical and computational investigation of adsorption and corrosion inhibition behaviour of 2-aminobenzohydrazide derivatives at mild steel surface in 15% HCl. Materials Chemistry and Physics. 2022;290:126666. Available from: https://doi.org/10.1016/j.matchemphys.2022.126666
Praveen BM, Alhadhrami A, Prasanna BM, Hebbar N, Prabhu R. Anti-Corrosion Behavior of Olmesartan for Soft-Cast Steel in 1 mol dm−3 HCl. Coatings. 2021;11(8):965. Available from: https://doi.org/10.3390/ coatings11080965
Guruprasad AM, Sachin HP, Swetha GA, Prasanna BM. Corrosion inhibition of zinc in 0.1 M hydrochloric acid medium with clotrimazole: Experimental, theoretical and quantum studies. Surfaces and Interfaces. 2020;19:100478. Available from: https://doi.org/10.1016/j.surfin.2020.100478
Prasanna BM, Praveen BM, Hebbar NBM, Pavithra MK, Manjunatha TS, Malladi RS. Theoretical and experimental approach of inhibition effect by sulfamethoxazole on mild steel corrosion in 1-M HCl. Surface and Interface Analysis. 2018;50(8):779–789. Available from: https://doi.org/10.1002/sia.6457
Praveen BM, Prasanna BM, Mallikarjuna NM, Jagadeesh MR, Hebbar N, Rashmi D. Investigation of anticorrosive behaviour of novel tert-butyl 4-[(4-methyl phenyl) carbonyl] piperazine-1-carboxylate for carbon steel in 1M HCl. Heliyon. 2021;7(2):e06090. Available from: https://doi.org/10.1016/j.heliyon.2021.e06090

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© 2023 Anbalagan et al. This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited. Published By Indian Society for Education and Environment (iSee)