Synthesis and characterization of Fe2O3-Bi2O3-TiO2nanoparticles and its magnetic properties

Tentu Manohra Naidu; P V Lakshmi Narayana  lowast

doi:10.17485/IJST/v13i18.90

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Indian Journal of Science and Technology

DOI: 10.17485/IJST/v13i18.90

Year: 2020, Volume: 13, Issue: 18, Pages: 1848-1855

Original Article

Synthesis and characterization of Fe2O3-Bi2O3-TiO2nanoparticles and its magnetic properties

Tentu Manohra Naidu¹ , P V Lakshmi Narayana^1∗

1 Department of Nuclear Physics, Andhra University, Visakhapatnam, 530003, A.P, India

∗Corresponding author:
P V Lakshmi Narayana
Department of Nuclear Physics, Andhra University, Visakhapatnam, 530003, A.P, India
Email: [email protected]

Received Date:01 April 2020, Accepted Date:18 April 2020, Published Date:17 June 2020

This work is licensed under a Creative Commons Attribution 4.0 International License.

Abstract

Objectives: The current research work was investigated magnetic properties of Fe2O3-Bi2O3-TiO2 nanoparticles (NPS). Methods/Statistical analysis: The Fe2O3-Bi2O3-TiO2 has been synthesized by a simple precipitation method. The samples were characterized by X-ray powder diffraction (XRD), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), Fourier-Transform Infrared Spectroscopy (FTIR) and UV-vis. absorption (reflectance) spectra. The magnetic properties of the magnetite nanoparticles were calculated by vibrating sample magnetometer (VSM) at ambient temperature. Findings: The effect of calcination on the magnetic and structural properties of Fe2O3-Bi2O3-TiO2 nanoparticles was studied. The Fe2O3-Bi2O3- TiO2 nanocrystal was subjected to calcination up to 200◦C, magnetite was converted to magnetite; the second transition was in the range of 300-400◦C which changed it to hard ferromagnetic hematite. Application/Improvements: This research provides promising results concerned with magnetic sensing probes for magnetic resonance imaging for in-vitro diagnostics and contrast agents.

Keywords: Fe2O3-Bi2O3-TiO2 NPs; Magnetic Properties; XRD; FESEM; VSM

References

Huang CC, Hung YH, Kuo MF. Investigation of the influence of raw material Fe2O3 on the magnetic properties of Sr-ferrite magnets. Funai Oyobi Fummatsu Yakin. Journal of Japan Society of Powder and Powder Metallurgy. 2016;63(7):636–642. doi: 10.2497/jjspm.63.636
Kawano S, Kosuge K, Kachi S. Electric and Magnetic Properties of “VO”. Journal of the Physical Society of Japan. 1966;21(12):2744–2745. doi: 10.1143/jpsj.21.2744
Noval VE, Universitaria C. Fe3O4 -TiO2 and Fe3O4 -SiO2 Core-shell Powders Synthesized from Industrially Processed Magnetite (Fe3O4 ) Microparticles. Materials Research. 2019;22(3):1–12.
Chirita M, Grozescu I. Fe2O3 - Nanoparticles , Physical Properties and Their Photochemical And Photoelectrochemical Applications. Chem Bull Politeh Univ Timsisoara. 2009;54(68):1–8.
Rymarczyk J, Hanc A, Dercz G, Ilczuk J. Mössbauer Spectroscopy X-Ray Diffraction and SEM Studies on Multiferroic Bi5Ti3FeO15Ceramics. Acta Physica Polonica A. 2008;114:1579–1584. doi: 10.12693/aphyspola.114.1579
Balamurugan S, Balu AR, Narasimman V, Selvan G, Usharani K, Srivind J, et al. Multi metal oxide CdO–Al2O3–NiO nanocomposite—synthesis, photocatalytic and magnetic properties. Materials Research Express. 2018;6(1):015022. doi: 10.1088/2053-1591/aae5af
Gich M, Frontera C, Roig A, Taboada E, Molins E, Rechenberg HR, et al. High- and Low-Temperature Crystal and Magnetic Structures of ε-Fe2O3and Their Correlation to Its Magnetic Properties. Chemistry of Materials. 2006;18(16):3889–3897. doi: 10.1021/cm060993l
Laurent S, Boutry S, Muller RN. Metal Oxide Particles and Their Prospects for Applications. (pp. 3-42) Elsevier Ltd. 2018.
Lomanova NA, Gusarov VV. Electrical properties of perovskite-like compounds in the Bi2O3-Fe2O3-TiO2 system. Inorganic Materials. 2011;47(4):420–425. doi: 10.1134/s0020168511040169
Guo X, Liu J, Guo G. Photocatalytic Removal of Dye and Reaction Mechanism Analysis over Y2O3 Composite Nanomaterials. In: MATEC Web Conference. 88:1–5.
Praveena K, Sadhana K, Srinath S, Murthy SR. Effect of TiO2 on electrical and magnetic properties of Ni0.35Cu0.12Zn0.35Fe2O4 synthesized by the microwave–hydrothermal method. Journal of Physics and Chemistry of Solids. 2013;74(9):1329–1335. doi: 10.1016/j.jpcs.2013.04.014
Singh SP, Karmakar B. Bismuth oxide and bismuth oxide doped glasses for optical and photonic applications. . In: In: Bismuth: Characteristics, Production and Applications. Materials Science and Technologies. (pp. 229-249) 2012.
Jartych E, Pikula T, Mazurek M, Franus W, Lisinska-Czekaj A, Czekaj D, et al. Structure and Magnetic Properties of Bi5Ti3FeO15 Ceramics Prepared by Sintering, Mechanical Activation and Edamm Process. A Comparative Study. Archives of Metallurgy and Materials. 2016;61(2):869–874. doi: 10.1515/amm-2016-0147
Wang F, Yu L. Corn-like, recoverable γ-Fe 2 O3-SiO2 @TiO2 photocatalyst induced by magnetic dipole interactions. Scientific Reports. 2017;7(1):2–11. doi: 10.1038/s41598-017-07417
Kaur N, Shahi SK, Singh V. Synthesis, characterization and photocatalytic activity of magnetically separable γ-Fe2O3/N,Fe codoped TiO2 heterojunction for degradation of Reactive Blue 4 dye. RSC Advances. 2015;5(76):61623–61630. doi: 10.1039/c5ra07812a
Gasmalla HB, Lu X, Shinger MI, Ni L, Chishti AN, Diao G. Novel magnetically separable of Fe3O4/Ag3PO4@WO3 nanocomposites for enhanced photocatalytic and antibacterial activity against Staphylococcus aureus (S. aureus) Journal of Nanobiotechnology. 2019;17(1). doi: 10.1186/s12951-019-0485-z

Copyright

© 2020 Naidu, Narayana. This is an open access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.
Published By Indian Society for Education and Environment (iSee)