Oxidation of Cinnnamic acid by Bipyridinium chlorochromate – Rate Determination at Various Concentration of Bipyridinium chlorochromate

Padma Priya   and Subramanium

doi:10.17485/ijst/2015/v8i32/89101

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Oxidation of Cinnnamic acid by Bipyridinium chlorochromate – Rate Determination at Various Concentration of Bipyridinium chlorochromate

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Indian Journal of Science and Technology

DOI: 10.17485/ijst/2015/v8i32/89101

Year: 2015, Volume: 8, Issue: 32, Pages: 1-6

Original Article

Oxidation of Cinnnamic acid by Bipyridinium chlorochromate – Rate Determination at Various Concentration of Bipyridinium chlorochromate

Padma Priya^1* and Subramanium²

¹Bharath University, Selaiyur, Chennai – 73, Tamil Nadu, India; [email protected]
² D.G. Vaishnav College, Arumbakkam, Chennai - 600106, Tamil Nadu, India

This work is licensed under a Creative Commons Attribution 4.0 International License.

Abstract

The kinetics of oxidation of cinnamic acid by BPCC in aqueous acetic acid (50%-50% v/v) in the presence of sulphuric acid has been studied. In order to arrive at a correlation between the synthetic efficacy and structure of reagent, the kinetics of oxidation of cinnamic acid with BPCC has been carried out in aqueous acetic acid. The reaction exhibit first order dependence on both the oxidant and substrate concentrations. In this part we have studied oxidation of cinnnamic acid by bipyridinium chlorochromate and determined rate at various concentration of bipyridinium chlorochromate.
Keywords: BPCC, Cinnamic Acid, Correlation, First Order, Mechanism